Near-Field Microwave Heating System and Method

ABSTRACT

A microwave heating device includes a variable frequency microwave power supply, a waveguide launcher, and a fixture to contain a material to be heated, with the fixture located directly adjacent to the end of the launcher. All heating occurs in the near-field region. This condition may be insured by keeping the thickness of the fixture or workpiece under one wavelength (at all microwave frequencies being used). The launcher is preferably a horn or waveguide configured to apply the microwave power to a small area to perform spot curing or repair operations involving adhesives and composites. The spot curing may secure components in place for further handling, after which a thermal or oven treatment will cure the remaining adhesive to develop adequate strength for service. A related method is also disclosed.

CROSS REFERENCE TO RELATED APPLICATION

The present application is a divisional of U.S. patent application Ser. No. 15/932,465 filed by the present inventors on Mar. 1, 2018, which is a continuation-in-part of U.S. patent application Ser. No. 15/731,881, entitled Near-Field Microwave Heating System, filed by the present inventors on Aug. 18, 2017, which further claims the benefit of Provisional Patent Application Ser. No. 62/497,062 filed by the present inventors on Nov. 7, 2016, the entire disclosures of which are incorporated herein by reference.

BACKGROUND OF THE INVENTION Field of the Invention

The invention pertains to apparatus and methods for heating materials with microwaves, and more particularly to spot-curing thermosetting materials using a near-field microwave applicator.

Description of Related Art

Microwave heating systems generally rely on a waveguide launcher that introduces microwave energy into an enclosed volume, referred to as a cavity. The cavity is typically metal, and the cavity walls enclose and define a volume of space in which microwave fields are established. The cavity may be tuned to support a single resonant mode, in which case it is typically cylindrical. Alternatively, the cavity may be multimode, in which many standing waves are established within the boundary conditions controlled by the size of the cavity, the load, and the wavelength of the microwaves. In either case, care is conventionally taken to place the load or workpiece well away from the near-field region directly adjacent to the waveguide or launcher.

Avoiding the near-field region is done for several reasons:

1. The workpiece is generally larger than the near-field region, so placing the part too close to the launcher will greatly increase the non-uniformity of heating. 2. Modeling the electric field distribution in a large multimode cavity is relatively straightforward for the far field case, whereas modeling in the near-field region is very difficult.

In variable-frequency microwave (VFM) heating systems, frequency sweeping is used to maintain a constantly-shifting pattern of standing waves in a multimode cavity, whereby an extremely uniform time-averaged power density is established throughout the working volume of the cavity. In conventional VFM systems, the multimode cavity is significantly larger than one wavelength in all three dimensions to allow for the establishment of many superimposed modes, as explained in detail in U.S. Pat. No. 5,961,871 to Bible et al. However, even in this case, the workpiece cannot be placed in the near-field region where the incoming power density is extremely high because it will prevent the microwave energy from fanning out and establishing the multitude of modes responsible for creating a uniform environment in most of the cavity.

The use of localized or near-field microwave heating has been suggested for a number of applications, such as localized tissue ablation for medical treatment, processing of foods, drying, and other purposes.

US 2015/0313273 to Stromotich et al. teaches a drying apparatus in which material to be dried is conveyed through an elongated cavity. Slotted waveguides extend into the cavity in the direction normal to the conveyor, and microwave energy emerging from the slots in the waveguides is applied to the material in the near field range of the slots.

US 2013/0150844 to Deem et al. discloses a hand-held device for locally treating living tissue by microwave heating. Cooling means are provided so that heating affects underlying tissues without burning the skin of the patient.

US 2011/0301588 to Cronin discloses an elongated microwave radiator with a monopole antenna at the tip, for insertion into a living body.

US 2009/0221999 to Shahidi discloses a handheld device for locally heating tissue, using a probe comprising a plurality of antennas, configured so that, by modifying the frequency or phase of individual antennas relative to one another, near-field interference effects can be used to tailor the pattern of the applied power density.

US 2005/0011885 to Seghatol et al. discloses a hand-held dental tool having a small antenna at its distal end to supply microwave power, taught to be generally less than 10 W at a preferred frequency from about 14 to 24 GHz, to cure dental resin for various restorative procedures.

U.S. Pat. No. 4,420,492 to Taylor discloses a method for shucking oysters by selectively heating the adductor muscle with microwaves. Microwaves are applied either by a small loop antenna or by an inwardly-tapering waveguide that concentrates the energy in a small region so as to heat the adductor muscle without cooking the rest of the contents of the oyster.

U.S. Pat. No. 6,191,402 to Ekemar discloses an RF heating system (50 kHz-299 MHz) in which a load to be heated is placed proximate to a generally planar antenna, disposed within a metal cavity. Ekemar teaches that frequencies below about 300 MHz provide advantages over microwaves, particularly in the depth of penetration into the material being heated. Ekemar further states that, “Favorable heating will be obtained if the cavity space is delimited. The cubic root of the cavity space volume shall not exceed 25% of any wavelength in vacuum conditioned by applied frequency . . . ”

The use of microwave energy to generate heat and/or enhance reaction kinetics in various organic reactions and catalysis is well known. A few exemplary disclosures include:

US 2012/0125920 to Novak discloses a method and apparatus for: (1) coupling of microwave energy from a microwave generator or plurality of microwave generators into an integral set of applicators; (2) extraction and separation of organic compounds from a mixture of organic and inorganic compounds; and (3) recovery and conversion of the organic compounds to gaseous and liquid fuels.

US 2014/0051775 to Kyle discloses a method of converting coal into a liquid hydrocarbon fuel utilizes a high pressure, high temperature reactor which operates upon a blend of micronized coal, a catalyst, and steam. Microwave power is directed into the reactor. The catalyst, preferably magnetite, will act as a heating medium for the microwave power and the temperature of the reactor will rise to a level to efficiently convert the coal and steam into hydrogen and carbon monoxide.

US 2015/0337224 to Stiegman discloses a method for the gasification of carbon to yield products including carbon monoxide, hydrogen, and methane. The method comprises irradiating a source of carbon with radiation having a frequency between 300 GHz and 300 MHz and contacting the source of carbon with a reactant such as water, carbon dioxide, hydrogen, and a nitrogen oxide. The choice of reactant dictates the resultant product.

U.S. Pat. No. 6,783,632 to Cha discloses a process for the efficient microwave catalysis production of hydrogen involving a modified steam-reforming reaction using light hydrocarbons or light alcohols as the basic reactant with supplementary oxygen to increase the efficiency.

U.S. Pat. No. 4,279,722 to Kirkbride teaches that petroleum refinery operations involving catalytic reactions are improved by subjecting hydrocarbon reactants in contact with catalytic material to the influence of wave energy in the microwave range.

The use of carbon fiber composites (CFC) to reduce weight in autos and trucks is driven by requirements for lower emissions and higher fuel economy. A major problem in use of carbon fiber composites for various components in an automotive assembly line is that conventional fasteners and tack welding cannot be used, so adhesive bond joints are typically used to join CFC components to CFC components and CFC components to metal components. However, the time to cure the adhesive joint can be 15-20 minutes, which is not compatible the pace of automotive assembly line production.

It is known that microwave heating can cure adhesives as much as ten times faster than convection oven or hot air heating. A microwave oven is not practical because of the size and the fact that conventional microwave energy is not uniform and will arc with metals and with carbon fibers in CFCs. What is needed, therefore, is a way to adhesively bond components within the time constraints of a typical automotive manufacturing environment so as to secure each assembly well enough to allow continued movement of the assembly down the production line.

Objects and Advantages

Objects of the present invention include the following: providing an apparatus for applying microwave power over a localized area while maintaining substantially near-field conditions; providing an apparatus for microwave-heated tack-bonding of polymer materials in a production line environment; providing an apparatus for localized microwave heating using a VFM source and a near-field applicator; providing an apparatus for curing adhesives and polymers over a localized area using a near-field applicator as a preliminary step to further curing of the same material over a more extended area; providing an improved method for composite bonding and field repairs; and providing fixturing methods for the safe application of microwave power to a selected surface area, which may be substantially flat or may have some degree of curvature. These and other objects and advantages of the invention will become apparent from consideration of the following specification, read in conjunction with the drawings.

SUMMARY OF THE INVENTION

According to one aspect of the invention, a microwave heating system comprises:

a variable-frequency microwave source;

a waveguide with an input side connected to the source and an output side terminating in a launch structure; and,

a fixture positioned to hold a curable adhesive material to be treated proximate to the launch structure so that a small portion of the material to be treated lies in the near field region of the launch structure.

According to another aspect of the invention, a microwave heating system comprises:

a variable-frequency microwave source;

a waveguide with an input side connected to the source and an output side terminating in a launch structure, the launch structure comprising a horn of selected dimensions; and,

a fixture located to hold a material to be adhesively bonded directly adjacent to the launch structure so that a first portion of the adhesive bond lies within one wavelength of the launch structure at the frequency being applied, so that it is cured by the microwave energy, and a second portion of the adhesive bond lies sufficiently far from the launch structure that it remains unaffected by the microwave energy.

According to another aspect of the invention, a polymer curing system comprises:

a variable-frequency microwave source;

a waveguide with an input side connected to the source and an output side terminating in a launch structure, the launch structure comprising a horn having selected lateral dimensions;

a compliant, microwave-absorbing structure around the periphery of the launch structure to sealably engage the surface of a workpiece, the workpiece having at least one polymer component to be cured over a selected area; and,

a fixture located to press the workpiece against the launch structure so that a first portion of the polymer component to be cured lies within one wavelength of the launch structure at the frequency being applied and a second portion lies outside the area of applied microwave energy, and the compliant structure is compressed against the workpiece to seal against microwave leakage.

According to another aspect of the invention, a method for microwave curing comprises the steps of:

providing a variable-frequency microwave source;

providing a waveguide with an input side connected to the source and an output side terminating in a launch structure, the launch structure comprising a horn having selected lateral dimensions;

applying an adhesive bonding material over an extended contact area between two components forming an assembly to be bonded, where the extended contact area is substantially larger than the area of the launch structure;

bringing the launch structure into contact with the assembly to be bonded; and,

applying microwave energy via the launch structure so that a localized portion of the extended contact area is subjected to microwave energy in the near-field region of the launcher while the remaining portion of the extended contact area is not.

According to another aspect of the invention, a method for microwave curing comprises the steps of:

providing a variable-frequency microwave source;

providing a waveguide with an input side connected to the source and an output side terminating in a launch structure, the launch structure comprising a horn having selected lateral dimensions;

applying at least two layers of fiber reinforced prepreg tape onto a supporting form of a selected shape forming a layup assembly to be cured, where the layup area is substantially larger than the area of the output face of the launch structure;

bringing the launch structure into contact with the layup assembly to be cured; and,

applying microwave energy via the launch structure so that a localized portion of the layup area is at least partially cured by microwave energy in the near-field region of the launcher while a remaining portion of the layup area is not cured.

BRIEF DESCRIPTION OF THE DRAWINGS

The drawings accompanying and forming part of this specification are included to depict certain aspects of the invention. A clearer conception of the invention, and of the components and operation of systems provided with the invention, will become more readily apparent by referring to the exemplary, and therefore non-limiting embodiments illustrated in the drawing figures, wherein like numerals (if they occur in more than one view) designate the same elements. The features in the drawings are not necessarily drawn to scale.

FIGS. 1A-B present a schematic diagram of one example of the present invention, configured to evaluate and perform catalytic processes involving a gas phase and a solid catalyst. FIG. 1A shows an elevation view and FIG. 1B shows a plan view of the exemplary system.

FIG. 2 illustrates one example of a wideband horn antenna compatible with a ridged waveguide.

FIG. 3 is a schematic diagram of another example of the present invention, configured to evaluate and perform catalytic processes involving a gas phase and a solid catalyst. In this configuration, a supplemental heating element is provided below the catalyst.

FIGS. 4A-C illustrate another example of the present invention, configured to position a wideband horn applicator for bonding and repair applications. FIG. 4A illustrates an overall view of the robot arm and microwave device. FIG. 4B shows how the entire microwave power supply and applicator assembly are attached to the end of the robot arm. FIG. 4C shows the microwave applicator viewed from another direction.

FIG. 5 illustrates another example of the invention, configured to apply microwave energy to a seam to be bonded.

FIG. 6 illustrates another example of the invention, having a flexible choke configured to apply energy to a lap seam while conforming to a workpiece having a larger vertical offset.

FIGS. 7A-B illustrate an example of a near-field applicator having an integral microwave choke and gasket arrangement. FIG. 7A presents an exploded view of the choke assembly; FIG. 7B shows the assembled choke engaging with a composite seam to be heated.

FIGS. 8A-B illustrate another example of a near-field applicator having an integral microwave choke comprising a boot/gasket combination arrangement. FIG. 8A presents a perspective view; FIG. 8B presents a cross-sectional view.

FIGS. 9A-B illustrate a mechanism for creating a near-field applicator within the chamber of a general purpose VFM cavity. FIG. 9A shows two H bends attached to the original launch port. FIG. 9B shows a fixture supporting a quartz tube for holding process gases.

FIG. 10 illustrates schematically an assembly having two components to be bonded, with a first portion of the bond area to be spot cured and a second, larger portion to be cured in a later operation.

FIG. 11 illustrates schematically the use of a small, near-field microwave applicator to expose a small portion of an adhesive to localized microwave energy while the remaining portion of the adhesive remains unexposed to microwaves.

FIG. 12 illustrates an assembly having a number of components spot-bonded into an assembly containing areas of uncured adhesive, ready to be fully cured in a subsequent treatment.

FIG. 13 illustrates schematically the steps of assembly, spot curing, and final curing.

DETAILED DESCRIPTION OF THE INVENTION

Generally, the inventive method employs a variable frequency microwave power supply, a waveguide launcher, and a fixture to contain a material to be heated, with the fixture/workpiece located directly adjacent to the end of the launcher. All heating occurs in the near-field region, i.e., no cavity modes or standing waves are established within the fixture or the workpiece. This condition may be insured by keeping the thickness of the fixture under one wavelength (at all microwave frequencies being used).

The launcher is preferably a horn configured to apply the microwave power locally over a selected area while maintaining a single propagating mode; to this end, the horn may contain ridges compatible with a ridged waveguide and operative over the selected microwave frequency range.

The fixture may comprise a means for pressing the launch structure securely against an article containing a polymer or adhesive to be cured. The article to be cured may include: polymer composites; carbon fiber composites; lap joints containing adhesive; lap joints in which one component is metallic; and composites having sections undergoing repair.

The fixture may further include a mechanically-compliant microwave choke to engage the workpiece surface and reduce microwave leakage. The fixture may further include a dummy load to absorb microwave power that has passed through the workpiece.

In electrical terms, prior art systems, whether fixed frequency or VFM, involve a cavity in which one or many modes are established, and the workpiece comprises a load, which is limited to some fraction of the total volume of the cavity and kept out of the near-field region so that well established cavity physics applies. The Q factor of the loaded cavity can, at least in principle, be calculated. Stub tuners or other devices may be placed in the waveguide to improve coupling to the cavity and reduce reflected power. Note that Applicants use the term “cavity” in the sense that is well understood within the microwave heating industry. As defined by Wikipedia, “A microwave cavity or radio frequency (RF) cavity is a special type of resonator, consisting of a closed (or largely closed) metal structure that confines electromagnetic fields in the microwave region of the spectrum. The structure is either hollow or filled with dielectric material. The microwaves bounce back and forth between the walls of the cavity. At the cavity's resonant frequencies they reinforce to form standing waves in the cavity.”

The invention, by contrast, represents a waveguide terminating directly onto the workpiece. There is, effectively, no cavity per se and the entire volume of the workpiece to be treated lies within the near-field region. Cavity physics does not apply because standing waves cannot be formed when the thickness of the fixture is less than half the wavelength. (Dimensions of the fixture and workpiece may be more than one wavelength in the two other directions, however, as Applicants postulate the tapering horn antenna effectively prevents the establishment of modes or standing waves in those directions.) The electrical circuit effectively created is instead analogous to a waveguide that simply terminates in a dummy load. Note that in one example, illustrated generally in FIGS. 9A-B, a larger cavity surrounds the entire assembly; however, because the inventive fixture effectively obstructs the normal opening of the launcher, it prevents the establishment of normal cavity modes that would form if the fixture and workpiece were not present.

Prior art VFM systems rely on the combination of frequency sweeping and standard cavity physics to establish a generally uniform time-averaged power density in the far-field part of the cavity (generally a few wavelengths away from the launch structure).

The invention, by contrast, contains only the near-field region, does not establish standing waves in a cavity, and uses frequency variation for a completely different function, viz., to more effectively excite gases or gas-solid interactions for catalysis and for other purposes. In an alternative mode, the invention may use frequency variation to speed chemical reactions in polymers and adhesives while avoiding arcing around metal components.

Several of the specific examples that follow describe particular systems and designs intended for use with a C band microwave source (5.85 to 8.20 GHz). It will be understood that these descriptions are exemplary in nature and Applicants do not intend for the invention to be limited to C band or to any particular bandwidth or sweep rate. The skilled artisan may easily modify the invention to operate at other frequencies by following well-known engineering design and modeling principles. In particular, variable frequency microwave sources employing traveling wave tube amplifiers, solid state power amplifiers, tunable magnetrons, etc., may be constructed to operate at a selected microwave frequency range of as much as an octave or more, or in a narrower band of, e.g, ±10%, ±5%, or ±1% around a selected center frequency. Exemplary microwave sources include the MG5349M tunable S-band magnetron [E2V Technologies Ltd., Chelmsford, England] having a frequency range of 2992 to 3001 MHz; the model K3C C-band compact klystron high power amplifier [CPI Satcom Division, Palo Alto, Calif.] having a frequency range of 5.850 to 6.425 GHz and instantaneous bandwidth of as much as 80 MHz; and the S5CI rack-mount SSPA [CPI Satcom Division, Palo Alto, Calif.] having a frequency range of 5.850 to 6.425 (optionally to 6.725) GHz. Frequency may be swept in a fairly continuous fashion through the operative bandwidth, swept in a series of discrete steps within the bandwidth, or hopped systematically or randomly from one frequency to another within the operative bandwidth depending on the needs of a particular process. Power may be held relatively constant or it may be varied during the process, either following a preset recipe or profile, or under active feedback control involving a process monitor.

Example

-   -   A system was designed to operate on C band, using a 2.0-8.0 GHz,         500 W S/C band rack-mount TWTA [Model VZS/C-2780C2;         Communications and Power Industries Canada, Inc., Georgetown,         Ontario]. High power output was delivered to the microwave         launcher through a standard WR137 ridged waveguide.

Those skilled in the art will realize that the aforementioned power supply has a very wide frequency range (2 octaves), and it will therefore be appreciated that other waveguides (e.g., WR430, WR340, WR284, WR187, etc.) may be suitable for particular frequency ranges.

Example

-   -   As shown schematically in FIG. 1, a horn antenna 11 [Model         137-441-2; L3 Narda-ATM, Patchogue, New York], was connected to         the WR137 waveguide 10. This horn has an output face 3.42×2.50         inches, and is 6.51 inches long. A microwave-transparent chamber         12 for holding catalyst material 13 is about 2.50×6 inches, so         that it is as wide as the narrow dimension of the horn, and         extends beyond the edges of the horn in the long direction. Gas         inlet 14 and outlet 15 ports are configured to allow selected         gases to pass through the catalyst in the long dimension (from         right to left as viewed in FIG. 1). The chamber 12 is preferably         longer than the catalyst 13 so that gases may expand before         entering the active catalytic region. The thickness of the         chamber in the direction normal to the output face of the horn         is preferably less than about 1 inch, and more preferably about         0.5-1.0 inch. This thickness is significantly less than one         wavelength over the relevant microwave frequency band (2.02-1.44         inches depending on the instant frequency).     -   Optional features include window 16 for measuring temperature         using an optical pyrometer, mass flow controller 17 for         controlling the flow of one or more gases, and heater 18 to heat         incoming reactant gases to a desired temperature.     -   As shown in FIG. 2, horn 11 preferably has internal ridges 21         analogous to and compatible with a ridged waveguide.     -   An auxiliary temperature-controlled heater [30 in FIG. 3] may be         used to preheat the entire sample to a selected temperature or         to provide supplemental heating in addition to the heat         generated by microwave absorption.

Applicants have discovered, surprisingly, that the inventive near-field applicator works very well, while clearly violating the guideline taught by Ekemar '402 to be necessary for constructing a near-field applicator. Specifically, in the example above, the volume of the horn and catalyst chamber is about 41 in³, and the volume of the catalyst chamber alone is about 15 in³; these volumes are significantly greater than the cube of the maximum wavelength (˜8 in³). Thus, in the present invention, near-field behavior is achieved by limiting the thickness of the catalyst bed to less than one wavelength, while exploiting an outwardly-tapering horn to expand the useful area to lateral dimensions significantly greater than one wavelength.

It will be appreciated that other horn geometries might be useful for other heating applications, as described in the following example.

Example

-   -   Another horn antenna [Model 137-444E-2; L3 Narda-ATM, Patchogue,         New York] has an output face with dimensions of 5.79×1.37         inches, and is 15.20 inches long. The elongated form factor may         be desirable for applications involving curing polymer adhesives         in composite lap joints, applying weather stripping, etc., where         there is no need to heat the rest of the workpiece other than         the adhesive bond line.

Example

-   -   The system illustrated schematically in FIG. 1 is particularly         suitable for performing various microwave-assisted chemical         reactions. This might be done in a continuous mode with a fixed         catalyst and a fixed gas mixture, e.g., for processing a toxic         off-gas stream, manufacturing synthesis gas or other products.         Alternatively, the catalyst may be fixed and the inlet gas         composition may be varied while analyzing the outlet gas         composition. In this mode, the system can be used as a research         tool to evaluate the interrelated effects of catalyst, microwave         parameters, and composition to better understand or develop         improved catalysts for use with a microwave heated reactor.

Example

-   -   In a more sophisticated research configuration, the fixture         could be divided into an array of individual cells containing         discrete catalyst samples and individual gas inlets and outlets,         so that a large number of catalysts could be evaluated in         parallel while holding gas composition and microwave parameters         constant.

Example

-   -   In another research configuration, the fixture might contain a         monolithic catalyst support, upon which different catalysts are         arranged in different areas. A thermal imaging device may be         positioned to observe the surface temperature distribution         during heating and gas exposure, in order to look for         differences that would be indicative of the relative performance         of the various catalytic areas. This mode would allow the         researcher to rapidly screen large numbers of catalyst         modifications and find those with attractive properties.

It will be appreciated that the invention may be used with virtually any suitable combination of gases and any type of solid catalyst including, but not limited to, supported catalysts, monolithic catalysts, platinum group metal catalysts, metal oxides, zeolites, and others. Gas reactions may include, but are not limited to: synthesis reactions, water-gas reactions, cracking, hydrogenation, oxidation, decomposition, and others. It will be appreciated that the gas pressure in chamber 12 may be controlled to a level that will support the formation of a plasma.

Thermal plasma can be characterized by a thermodynamic equilibrium, with all species (electrons, ions, and neutral species) having the same temperature (energy). An example for thermal plasma is arc plasma and its temperature may be around 10,000 K. Non-thermal plasmas are characterized by a non-equilibrium between the temperature of the electrons and the ions. The temperature of the electrons ranges between several electron volt (eV), whereas the temperature of the positively charged ions and neutral species is significantly colder (about room temperature) leading to a very low overall temperature. Therefore, non-thermal plasmas, also called non-equilibrium plasmas, are favorable for the synthesis of materials (e.g., nanoparticles) at low temperatures.

Combining the two processes leads to plasma catalysis, which is an emerging technology that holds promise for improving existing technologies for numerous applications which include but are not limited to: air purification, hydrocarbon reforming, synthesis of nanomaterials, hydrogen production and ammonia production. The advantages of plasma catalysis over traditional catalysis are enabled by combining the high reactivity of the plasma with the high selectivity of the catalyst. The aim of plasma catalysis can be described as generating reactive species in the plasma and allowing them to react at the catalyst surface, forming the desired products with high conversion efficiencies and very high selectivity and at a low energy cost.

When catalysts are combined with plasmas, they are usually incorporated into non-thermal plasma. The catalyst is placed either inside the plasma (in-plasma catalysis) or after the discharge zone (post-plasma catalysis). Some studies show that the catalyst can be more effective at increasing gas conversion efficiencies when placed inside the plasma. In either case, the plasma can be used to supply energy for catalyst activation and it can also provide the reactive gas species needed for reactions on the catalyst surface.

For in-plasma catalysis, the catalyst is in contact with the discharge and, therefore, is also in contact with the short-lived excited species, radicals, photons, and electrons. In the post plasma catalysis, the catalyst is only exposed to the long-lived species that exit the discharge. The catalyst material can be typically introduced in the form of pellets, honeycomb monoliths or foams.

Depending on the interest with short-lived or long-lived species, the inventive applicator can allow both in-plasma catalysis with a single system, and post-plasma catalysis with two identical systems having independent controls.

The inventive near-field applicator also has applications in joining and repair operations in which a polymer is to be cured quickly. Examples include adhesive bonding (metal-to-metal, metal-to-polymer, or polymer-to-polymer), repair of polymer-matrix composites (fiberglass or carbon fiber reinforced); spot-curing of thermosetting patches and fillers; localized heating of thermoplastics for bonding or other purposes; and localized curing to tack an assembly together before moving it to a larger oven to do the final curing.

Exemplary thermosetting polymers include: epoxies, phenolics, polyesters, silicones, vulcanized rubbers, methacrylates, and methyl methacrylates, It will be appreciated that some thermosets will cure slowly at temperatures as low as ambient (˜20° C.) but in a production environment the cure temperature might range from about 80-150° C. to speed the curing.

Exemplary thermoplastic polymers include: polyethylene, polypropylene, polybutylene, polyim ides, and polyam ides.

Example

-   -   An epoxy structural adhesive, SikaPower® 477R, [Sika         Corporation, Madison Heights, Mich.] was applied between two         carbon-fiber composite strips. The two strips were placed one         over the other to form a lap joint of ˜7 cm² and heated in VFM         for 80 seconds. The resulting cured lap bond was sound and had         adequate mechanical strength.     -   Similar bonding between an aluminum and carbon-fiber composite         specimen was also accomplished in VFM in 130-150 seconds,         yielding a strong bond.     -   Metal studs bonded to carbon-fiber composite using the         aforementioned adhesive had significant bond strength (i.e.,         were capable of handling a relatively high torque when a nut was         tightened onto them). These runs were performed in a VFM         multimode chamber.

Example

-   -   Similar composite to composite experiments have also been         performed with a near field VFM applicator. No damage to the         carbon fiber composite was observed in either of these         approaches. However, when fixed frequency microwave experiments         were performed with the near field applicator certain spots on         the composite overheated and the fiber bundles were delaminated.         These results demonstrate that VFM confers favorable process         characteristics even in the absence of a traditional multimode         cavity environment.

Example

-   -   Automobile assembly typically involves a high degree of         automation, with large robots capable of holding robust tooling         to perform welds or other operations on chassis and body         components held in customized fixtures. FIG. 4A shows a         conventional factory robot 40 [Model IRB 7600, ABB Robotics,         Affolternstrasse 44, Zurich, Switzerland] with a microwave         system 41, as generally described above, mounted on the movable         arm 42 so that the horn may be brought into contact with a         workpiece (not shown). The arm 42 is capable of supporting the         launch structure and controllably moving it into a selected         position in contact with the assembly to be treated. FIGS. 4B-4C         show the microwave device in more detail. Here, the power supply         44 and horn assembly 43 are all arranged on a common platform         45, which then hangs rigidly from the end of the arm.

Example

The system shown in the preceding example might be used, for example, to join a weather strip assembly to a metal door frame using a thermoset adhesive applied over an extended contact area. The horn applicator would be brought down to apply pressure and microwave energy to a localized portion of the weather strip assembly to locally spot-cure the adhesive or “tack” the strip into place while a second portion of the adhesive bonding material remains uncured; the process would be repeated at enough other places to secure the assembly in its desired pattern. Then, the entire assembly could be moved into a larger oven (which may accommodate racks with many such assemblies) for a longer cure to complete the adhesive bond around the entire periphery of the door frame.

FIGS. 10-12 show the concept of spot curing or “tacking”, in which an assembly 101 includes components to be joined 102, 103 having a layer of thermoset adhesive 104 applied along an extended contact area. As shown in FIG. 11, a small applicator 43 is brought into contact with the assembly and briefly applies microwave energy to a small spot to cure a first portion 105 of the adhesive 104 while the remaining portion 104′ of the adhesive bonding material remains uncured. This may be repeated at one or more other spots as needed to temporarily secure the adhesive joint and give the assembly adequate strength to proceed to further operations, after which a final thermal treatment cures the remaining adhesive to develop the ultimate strength needed for service. The process steps are illustrated schematically in FIG. 13.

Applicants contemplate that a preferred system will spot cure only enough of the adhesive joint to ensure adequate structural integrity for subsequent handling, after which the assembly will receive a final (oven or IR) cure. Any one spot treatment will therefore represent preferably less than 20%, and more preferably less than 10% of the total area that will ultimately be adhesively bonded. The number of spots to be cured may vary with the size of the upper component 103, as shown generally in FIG. 12, which shows schematically that small components 103″ may get one spot in the center, larger components 103′ may get a spot at each end, and still larger components 103 may get more spots, e.g., a spot every 10-30 cm. Similarly, irregularly shaped components (not shown) might get spot cures near bends, etc.

Example

-   -   In many cases, Applicants contemplate that the applicator will         essentially straddle the lap joint, as shown generally in FIGS.         5-7. The reason is that it is difficult to penetrate a cross-ply         CFC because the electrical conductivity of the fibers creates a         surface that is relatively opaque to the passage of microwaves.         In previous work, Applicants discovered that cross-ply CFCs         could be VFM cured as long as an edge is exposed to the         microwave energy. Applicants speculated that enough independent         microwave frequencies and modes were excited through VFM that at         least some energy could propagate parallel to the carbon fibers,         perhaps in a quasi microstrip mode.     -   For cases where it is desirable to launch the microwaves through         the top composite, rather than into an edge, Applicants         contemplate that a small hole 106 may be drilled through the top         laminate 103″ as shown schematically in FIG. 12 (preferably as a         prior operation rather than after it has been pressed onto the         adhesive layer). When the microwave launcher 43 is placed over         this pre-drilled hole 106, the microwave energy can therefore         pass down into the adhesive layer and then propagate radially         outward, guided by the plies as was earlier noted in cross-ply         CFC laminates. The relatively high loss tangent of the uncured         adhesive will help limit the cured area to the desired size, and         the user may determine the optimal hole diameter through routine         experimentation based on such factors as the frequency range,         resin properties, fiber conductivity, and the like.     -   It will be appreciated that the drilled hole will not be         necessary if the top component is a fiberglass composite, which         is substantially transparent to microwaves.

Applicants contemplate that with proper formulation of the adhesive material the final cure may be carried out simultaneously with an existing step of baking a primer coat on the finished assembly as illustrated schematically in FIG. 13. As an example, ChromaGLAST™ epoxy primer/sealer [Fibre Glast Developments Corp., Brookville, Ohio] typically cures in 60-120 minutes at 70° F., or 25 minutes at 140° F. So in this case, an adhesive may therefore be selected that will cure at 140° F. simultaneously with the primer curing. Other cure temperatures may be selected by the user depending on the combination of adhesive and primer that are selected by the user.

It will be appreciated that the area of the adhesive bond that is fully cured by the microwave spot treatment may be slightly larger or slightly smaller than the aperture of the launch structure 43. The reasons for this may include a thermal gradient that reduces the temperature of the material around the periphery of the area being irradiated, or conversely, propagation of microwaves outward in a direction parallel to the bond line. However, because the uncured thermoset resin tends to be very lossy, it is not expected that curing will extend outward much beyond the “footprint” of the applicator.

In this context, it will be clear that when Applicants refer to “material to be cured” or “material to be treated”, this means material to be cured in that particular heating cycle. In other words, an extensive bond line might be treated, as described above, in a series of discrete spots. The material to be cured in one particular cycle will therefore be that portion of the material that is under the applicator at the time, and all of that material will lie within one wavelength of the applicator (measured in the direction of microwave propagation).

Example

-   -   In another example, the horn 43′ might be configured to be         significantly elongated in one direction relative to the         orthogonal direction, as shown generally in FIG. 5. This         configuration could be used when a long lap joint or seam is to         be cured in situ without a later oven cure.

Example

-   -   In order to reduce or eliminate microwave leakage, a microwave         choke 50 may be provided to sealably engage the workpiece         surfaces 51, 52 and allow the horn to conform to the step         associated with the lap joint 53, as shown in FIG. 5. The         microwave choke may contain one or more microwave-attenuating         structures 63, including: conductive sheet metal strips such as         copper or beryllium copper alloys; woven stainless steel or         compressible Monel gaskets, compliant silicone rubber filled         with conductive particles, or lossy foam materials such as the         MF2 product series [Mast Technologies, San Diego, Calif.], etc.,         as are well known in the art.     -   When lossy foam materials are be used, a flange 61 may be         provided that surrounds the horn 43″ or waveguide 62 opening and         extends outward for a selected distance so that lossy foam or         other microwave attenuating element 63″ may be affixed to the         flange as shown generally in FIG. 7. The width of flange 61 will         therefore control the effective distance that microwaves will         have to travel laterally within the lossy material before         escaping, so that a wider flange will provide greater         attenuation as well as a more extensive surface upon which to         secure the lossy material 63″.

Example

-   -   FIG. 6 is a schematic illustration of a fabricated applicator as         a variant of the horn shown in FIG. 5. In this case, a flange 61         surrounds the waveguide opening (applicator) 43″ and extends         outward for a selected distance where a large flexible boot 63′         comprises a bellows-like arrangement for the most         compressibility that allows conformal contact to a large         vertical mismatch at lap joint 53′ such as that shown in FIG. 6.         A flexible boot was cast out of conventional two-part RTV         silicone and a conductive coating [Flexible, High Temperature,         Electrically Conductive Coating 124-47 by Creative Materials, 12         Willow Road, Ayer, Mass. 01432] was sprayed both on the inside         and outside of the boot and cured for 2 hours at 150° C. The         flexibility of the silicone boot made good contact at the lap         joint offset, so it could seal well for microwave leakage.         However, the sprayed conductive coating which had fairly good         conductivity (low resistance ˜10 ohms) right after cure did not         bond well to the silicone substrate and started to peel and         flake off during the compressive movement of the bellows-like         boot.     -   To overcome the bonding issue one approach would be to fabricate         the boot from a continuously co-extruded highly conductive metal         filled silicone outer layer on a high-strength silicone rubber         core [Dual Elastomer ULTRA-VANSHIELD, U.S. Pat. No. 4,968,854 by         Vanguard Products Corporation, 87 Newtown Road, Danbury, Conn.         06810 USA].

Example

-   -   FIG. 7A is a schematic of a fabricated applicator where a flange         61 surrounds the waveguide opening (applicator) 43″ and extends         outward for a selected distance where the 12 mm compliant         ULTRA-VANSHIELD® P gasket 63″ (shaped into a rectangle shown         between the applicator and composite in FIG. 7A) is affixed to         the flange. As shown in FIG. 7B, when the         waveguide/applicator/gasket assembly is compressed against the         workpiece 51, 52 the elastomer, with its optimum combination of         metallic conductivity and elastomeric properties, makes a         conformal contact between the workpiece and applicator flange,         thereby sealing the microwave leakage. When either fixed         frequency or variable frequency microwave (VFM) power (180 W)         was delivered into applicator 43″, the microwave leakage was         found to be 0.15 mW/cm² on the top or applicator side of the         workpiece. On the bottom side of the workpiece the microwave         leakage was not even detectable. A fiber optic probe was         attached to a composite coupon to determine the temperature.         With VFM the fiber optic recorded a temperature of 172° C.,         whereas with fixed frequency at 5.85 GHz the temperature was         only 78° C. at the fiber optic probe. However, during this fixed         frequency run another area heated much more than the area where         the fiber optic probe was attached. The temperature difference         was easily sensed by touching the bottom side of the workpiece.         On cooling and examining the composite corner had overheated         sufficiently to decompose the polymeric resin and delaminate the         carbon fiber layers. These hot and cold spots commonly observed         with fixed frequency in larger multimode ovens are also probable         in smaller near field heating applications. For this reason,         Applicants prefer to employ some degree of frequency sweeping         (at least ±1%) despite the fact that the applicator doesn't         employ a resonant cavity.

Because of the high shielding effectiveness, low compression force, resistance to permanent compression set, as well as the ability to create at least a partial environmental seal, a smaller diameter gasket was tested as a microwave cavity door seal. The door was cycled 100,000 times and there are no significant signs of wear on the outer conductive layer and hence no degradation in the microwave sealing capability. In view of these properties Applicants contemplate that one could fabricate an absorber with such a material or a combination of multiple ULTRA-VANSHIELD (O-ring) gaskets in an absorbing silicone boot. FIG. 8A shows the isometric view and FIG. 8B the cross-sectional view of a stack of gaskets 70 of varying diameters providing the electrical contact whereas the outer boot 71 houses and holds the gaskets in place. The flexibility of the boot and compressibility of gaskets will allow sealing of joints with larger lap offset in a manner analogous to the single ring demonstrated in the foregoing example.

Although conventional microwave devices may use various microwave chokes around door openings or around incoming and outgoing conveyors, for example, such chokes are generally not intended to be brought into direct contact with the material being heated. Applicants therefore contemplate a unique choke design that meets several requirements: First, it is sufficiently compliant to engage a surface that may be curved and/or may contain a lap joint or other feature that requires sufficient compliance to conform to a surface that is not perfectly planar. Second, the choke will to some degree be subjected to heat, either conducted from the workpiece, which is being actively heated, or generated within the choke materials by the microwave leakage being attenuated.

Example

-   -   One way to meet these two requirements is to provide a         water-filled tube or bladder structure surrounding the periphery         of the waveguide. The bladder would be inflated with water and         act like a balloon that will deform when compressed and thereby         conform to a wide variety of surfaces. The water is an excellent         microwave absorber and will thereby enhance the microwave         attenuation. Furthermore, the water may be recirculated to         prevent heat buildup in the choke and applicator assembly.

Example

-   -   In some applications, the bonded area may be of fairly limited         size, or it may comprise a seam that is narrow and also curved,         e.g., around the door frame of a car. In such applications, a         wide or elongated horn may be impractical. For spot curing,         therefore, the horn may be eliminated and the inventive         microwave choke may simply be disposed around the open end of         the waveguide itself. Again, this has the electrical effect of a         waveguide terminating in a dummy load. It will be appreciated         that the waveguide in this case might or might not be a ridged         waveguide, and if it is a ridged waveguide, the internal ridges         might be tapered for some distance leading up to the end in         order to enhance the power uniformity over the entire area of         the waveguide where it engages the workpiece.

Example

-   -   The inventive device may be used as follows:     -   1. Articles to be joined are held in a fixture with an adhesive         layer in the joint space;     -   2. The robot arm positions the horn over the area of the joint         to be cured;     -   3. The horn is pressed downward to apply pressure to the         adhesive bond and to the compliant microwave choke;     -   4. Microwave power is applied for a sufficient time to create an         adhesive bond of adequate strength; and,     -   5. If desired, the microwave horn is moved to another place on         the workpiece and the process is repeated.

Example

-   -   It will be appreciated that the invention may equally well be         carried out in an alternate configuration in which the microwave         power supply is stationary and the workpiece is held by the         robot arm. In such cases, the robot would move the part and         bring the area to be heated into contact with the (stationary)         microwave applicator horn.

Example

-   -   The inventive device may be used for field repair or patching,         e.g., when an area on the surface of a polymer composite         aircraft structure or boat hull has been damaged. In this case,         the method might include the steps of:     -   1. Clean the damaged area and remove any cracked or defective         material;     -   2. Apply a curable polymer patch, prepreg laminate, or a mixture         of polymer and fiber cloth;     -   3. Optionally provide a separation layer or protective film to         prevent adhesion between the horn and the patch material;     -   4. Press the horn against the patch to provide pressure to the         adhesive joint and engage the microwave choke;     -   5. Apply microwave power to cure the patch material.

Example

-   -   Many fiber-reinforced composites are built as layups of several         layers of prepreg tape. A particular tape may be a single ply         with substantially unidirectional fibers, and then laminated         into a multilayer structure that may be unidirectional or         cross-ply depending on how subsequent plies are laid upon the         previous ply. In many cases, such layups are built on a form or         mandrel that defines the desired shape of the finished product,         such as a boat hull, airplane wing, car fender, or the like.     -   In such cases, the form may be large and costly and it is         therefore desirable to remove one layup from the form so that         another may be built while earlier layups are curing, e.g., in a         dedicated oven, IR tunnel, or other suitable means. However,         when the layup is first put together, bonding between plies is         extremely weak and the uncured layup is in general not strong         enough to be removed from the form keep its shape during further         handling. In such a case, a layup may be formed and the         inventive applicator, preferably manipulated by a robot as shown         schematically in the various FIGs. herein, may be brought into         contact to spot cure a sufficient number of points around the         surface to give the component adequate mechanical integrity for         removal from the form for further handling and curing.     -   If the layup comprises a carbon-fiber composite, application of         microwave energy will preferably be done at selected points         around the periphery, in order to allow the microwaves to         penetrate between the layers. In this case, the fixture will         preferably have a metal edge extending outwardly beyond the edge         of the layup, and the applicator will therefore straddle the         edge in a manner analogous to that shown in FIGS. 5-7. If the         layup involves multiple layers of unidirectional prepreg tape,         one could spot cure after each layer, and in that case the         applicator may be rotated so that the direction of polarization         is oriented favorably with respect to the carbon fibers so that         microwaves can penetrate through the top tape layer.     -   If the layup comprises a fiberglass composite, then the entire         layup can be constructed and spot curing can be done at any         selected points because the microwaves will penetrate the entire         depth of the layup.

Example

-   -   It will be appreciated that multilayer prepreg layups are often         optimally cured via the application of pressure as well as heat.         In this case, the microwave applicator may include a dielectric         window covering the output face of the horn or waveguide so that         uniform pressure is applied normal to the surface during         microwave heating. A suitable non-stick coating or disposable         separation layer may further be provided to prevent the         microwave applicator from adhering to the workpiece as the resin         is cured.

Example

-   -   An additional application for the technique described is to         adapt the same small applicator for repair of carbon fiber         composites following damage (e.g., after an automobile         accident). If thermoplastic adhesives are used for the assembly,         the same applicator may be used to de-bond an area, replace or         repair the damaged section, and then bond the joint again.

Example

-   -   For spot repairs, particularly when each job is likely to be         different and the use of robots and/or standardized tooling is         impractical, it might be desirable to separate the horn from the         power supply so that the generally heavy power supply is         stationary or contained in a rolling cart or dolly. The horn, in         this case, would then be configured to accept a coaxial input         cable, which would allow a very flexible connection (in contrast         to the rigid waveguide shown in other examples). Then, the         operator would hold the horn and place it manually against the         surface being repaired; a safety interlock will preferably be         arranged on the output face of the horn so that microwave power         will not be activated unless the microwave choke is securely         seated onto the workpiece.     -   The invention may be further modified for even greater         versatility by providing various horn applicators optimized for         different repair jobs. For example, the output face of one horn         may be flat, whereas others may be shaped to conform to various         radii as might be encountered on the surfaces of aircraft or         pleasure boats. Different sizes of horns and different operating         frequencies might be better suited to different workpieces,         e.g., one size and frequency range for repairing fiberglass         composites and a different size and frequency range for         repairing carbon fiber composites. Each launcher might have the         same type of coaxial input so they can be easily exchanged on a         common power supply. Alternatively, several applicators may be         permanently connected to the power supply, with a microwave         switch configured to select a particular applicator for a given         job.

Example

-   -   A straight waveguide was connected to the power supply described         above and extended into the chamber of a MicroCure 5100         microwave processing system [Lambda Technologies, Morrisville,         N.C.]. The waveguide terminated 0.25 in. above the sample, which         consisted of a lap joint formed between an aluminum plate and a         carbon fiber composite. The aluminum was on the bottom, and a         small coupon of aluminum was placed under the far end of the         carbon fiber composite to support it in a horizontal position         parallel to the aluminum plate. The sample was manually         compressed to distribute the thermoset adhesive across the joint         surface, but no pressure was applied during processing. Thermal         paper was placed under the assembly and several fiber optic         temperature probes were placed proximate to the lap joint.     -   Microwave power was swept over the frequency range 5.85-6.65         GHz; 400 W was applied for 35 seconds. Temperature directly         under the waveguide reached 250° C.; the temperature about 2         inches away, under the aluminum plate, was about 93° C.         Darkening of the thermal paper showed that the area of the lap         joint was efficiently and uniformly heated. Upon cooling, the         sample showed good adhesion.

Example

-   -   A similar lap joint assembly was treated using a horn antenna         placed 1 inch above the lap joint and oriented with the long         axis of the horn parallel to the long axis of the specimen, so         that it covered the bond area along with a portion of the         substrates on either side of the lap joint.     -   Microwave power was again swept over the range 5.85-6.65 GHz;         400 W was applied for 50 seconds. The maximum temperature         directly at the lap joint was 220° C.; the temperatures on         either side were about 100° C. under the aluminum and 86° C.         under the composite. The thermal paper again indicated thorough         and uniform heating of the lap joint. The adhesive bond was good         and showed no visible burns.

In some of the examples described above, it was contemplated that the microwave choke would be a somewhat compressible structure, which would serve the dual purpose of sealably engaging the workpiece and also applying mechanical compression to a composite or adhesive joint during cure. For situations in which mechanical compression is not needed, Applicants have discovered a surprisingly effective and inexpensive shielding strategy as described in the following example.

Example

-   -   Using the setup previously described, with a straight waveguide         terminating just above the workpiece, a skirt of conductive         fabric was clamped around the waveguide so that it draped over         the workpiece. With the microwave power on, there was no         microwave leakage detected in an opening about 6 inches away         from the waveguide in the rear of the VFM chamber. Suitable         conductive fabrics include Ni—Sn plated conductive polyester         [MEA series, E-Song America, Campbell, Calif.].

For applications where higher temperatures might degrade conductive cloth, a flexible elastomeric sheet may be used. One example of such a product is the Surface Wave Absorber product series, e.g., MR31-0004-20 [MAST Technologies, San Diego, Calif.].

As discussed earlier, in a conventional multimode VFM system, uniformity is achieved by establishing many, rapidly changing, mode patterns within the cavity. It follows from this that conventional VFM systems are configured to avoid placing the workpiece in or near the microwave launcher, to avoid near-field effects. However, there may be situations in which a user might wish to do controlled near-field experiments from time to time in an otherwise general-purpose VFM oven such as the Vari-Wave II [Lambda Technologies, Morrisville, N.C.]. It is therefore desirable to have a separate tool or accessory that can be removably mated to the existing system to run such tests.

Example

-   -   A conventional multimode VFM system may be modified as follows         so that near-field experiments can be carried out conveniently.         A horn structure as shown generally in FIGS. 1 and 3 may be         constructed of a size that can be installed within the VFM         cavity. The inlet waveguide (shown at the top in FIGS. 1 and 3)         would be of a size and shape to slide into or otherwise engage         the existing microwave launcher in the VFM cavity and thereby         convey the microwave power and spread it over a larger area         while maintaining near-field propagation characteristics.

Example

-   -   To demonstrate the ability to perform near-field heating in a         general-purpose VFM cavity 80, in which the existing launcher is         on the rear wall of the chamber, two standard waveguide H bends         82 were attached to direct power to a waveguide launch in the         middle of the chamber as shown generally in FIG. 8A. A fixture         83 was constructed to support a quartz tube 84 through which         process gases could be passed as shown generally in FIG. 8B. 

We claim:
 1. A method for microwave curing comprising the steps of: providing a variable-frequency microwave source characterized by a center frequency and a usable bandwidth about said center frequency; providing a waveguide with an input side connected to said source and an output side terminating in a launch structure, said launch structure comprising a waveguide opening having selected lateral dimensions; applying an adhesive bonding material over an extended contact area between two components forming an assembly to be bonded, where said extended contact area is substantially larger than the area of said launch structure; bringing said launch structure into contact with said assembly to be bonded; and, applying microwave energy via said launch structure so that a localized portion of said extended contact area is cured by microwave energy in the near-field region of said launcher while a remaining portion of said adhesive bonding material over said extended contact area is not cured.
 2. The method of claim 1 wherein said usable bandwidth is at least ±1% of said center frequency.
 3. The method of claim 1 further comprising the step of: moving said launch structure sequentially from one spot to another along the surface of said assembly so that said adhesive bond may be spot cured at a sufficient number of points to provide adequate structural integrity for further handling.
 4. The method of claim 1 wherein said localized cured portion represents no more than 20% of said extended contact area.
 5. The method of claim 1 further comprising the step of: heating the entire assembly to a temperature sufficient to cure said remaining adhesive material.
 6. The method of claim 1 further comprising the steps of: applying a coating to said assembly; and, heating the coated assembly at a temperature sufficient to bake said coating and simultaneously cure said remaining adhesive bonding material.
 7. The method of claim 1 wherein said assembly to be bonded comprises at least one material selected from the group consisting of: metal-to-metal, metal-to-polymer, and polymer-to-polymer adhesive bonds; fiberglass- and carbon-reinforced polymer-matrix composites; and thermosetting resins.
 8. The method of claim 1 further comprising the step of: providing an opening through the thickness of one of said two components so that when said launch structure is placed over said opening, the applied microwave energy can pass through said opening and into said adhesive bonding material.
 9. The method of claim 1 wherein said adhesive bonding material comprises a thermosetting polymeric material selected from the group consisting of: epoxies, phenolics, polyesters, silicones, vulcanized rubbers, methacrylates, and methyl methacrylates. 